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On 9 December, 2016, Cole released his fourth studio album "4 Your Eyez Only". Cole: Road to Homecoming" in the period of Decem– Janu& "Forest Hills Drive: Homecoming" on January 9, 2016. The album was later accompanied by two documentaries "J. The latter earned him his first Grammy Award nomination for Best Rap Album. The album debuted at number one on the Billboard 200, selling 353,000 copies in its first week and was certified platinum on March 31, 2015. It was also the first album in 25 years at that time that went 3 times platinum with absolutely no features. On December 9, 2014, Cole, released his third studio album "2014 Forest Hills Drive". The album was supported by the lead single Power Trip with R&B artist Miguel, which was released on February 14. On September 15, 2020, Born Sinner was certified double platinum. The album received mostly positive reviews from critics. Born Sinner sold 297,000 copies in its first week of release, and peaked at number one in it's third week of release. In June 18, 2013, Cole released his second studio album Born Sinner. Billboard 200, and was soon certified platinum by the Recording Industry Association of America (RIAA). Intent on further pursuing a solo career as a rapper, he went on to release two additional mixtapes The Warm Up in 2009 and Friday Night Lights in 2010, after signing to Jay Z's Roc Nation imprint in 2009.Ĭole released his debut studio album, Cole World: The Sideline Story, on September 27, 2011, which included the lead single "Work out". Born in Frankfurt, Germany, Raised in Fayetteville, North Carolina, Cole posted songs on various internet forums at the age of 14 under the name "Blaza", but later switched to the name "Therapist".Ĭole initially gained recognition as a rapper following the release of his debut mixtape, The Come Up, in early 2007 in which he also founded his record label Dreamville with label president Ibrahim Hamad. Cole, is an American hip hop recording artist and record producer. … Read Full Bio Jermaine Lamarr Cole (born January 28, 1985), better known by his stage name J. Jermaine Lamarr Cole (born January 28, 1985), better known by his stage name J. These salts all actually exhibit the sodium chloride lattice (CN 6). ΔH 3 = dissociation energy of Cl 2(S) = 244 kJ mol –1 1 atom at the corners, a total of 4 atoms. ΔH 2 = ionisation energy of Na(S) = 495.0 kJ mol –1 ΔH 1 = heat of sublimation of Na(S) = 108.7 kJ mol –1 ΔH f = heat of formation of sodium chloride = – 411.3 kJ mol –1 Let us calculate the lattice energy of sodium chloride using Born-Haber cycle The sum of the enthalpy changes of these steps is equal to the enthalpy change for the overall reaction from which the lattice enthalpy of NaCl is calculated. Also, the formation of NaCl can be considered in 5 steps. Since the reaction is carried out with reactants in elemental forms and products in their standard states, at 1 bar, the overall enthalpy change of the reaction is also the enthalpy of formation for NaCl. Let us use the Born - Haber cycle for determining the lattice enthalpy of NaCl as follows: ˆ†H f - enthalpy change for the formation of solid MX directly form elements According to Hess's law of heat summation U - the lattice enthalpy for the formation of solid MX ˆ†H 3- Ionisation energy for M(g) to M +(g) ∆H 4 - electron affinity for the conversion of X(g) to X -(g) ΔH 2- enthalpy change for the dissociation of ½ X 2 (g) to X(g) ˆ†H 1 - enthalpy change for the sublimation M(s) to M(g) For example consider the formation of a simple ionic solid such as an alkali metal halide MX, the following steps are considered. The equation is: Lattice enthalpy Heat of formation- Heat of sublimation- (1/2 Dissociation energy) - (sum of Ionization energies)- (sum of Electron Affinities) How do you calculate. The Born–Haber cycle applies Hess's law to calculate the lattice enthalpy. Lattice Energy is directly proportional to the Charge on ion and inversely proportional to radius of atom. The cycle is concerned with the formation of an ionic compound from the reaction of a metal with a halogen or other non-metallic element such as oxygen.īorn–Haber cycle is primarily used in calculating lattice energy, which cannot be measured directly. It was named after two German scientists Max Born and Fritz Haber who developed this cycle. 9.The Born–Haber cycle is an approach to analyse reaction energies.Calculate the lattice energy for CaF 2.Įnergy of formation for one mole of CaF 2 from its elements = -1228 kJ/molīack to Periodic Trends and Ionic Compounds The sublimation energy for Sr is 164 kJ/mol, E i1 = +549.5 kJ/mol, E i2 = +1064.2 kJ/mol, E ea for Cl (g) = -348.6 kJ/mol, energy for the formation of one mole of SrCl 2 from its elements = -803.7 kJ/mol, and the bond dissociation energy for Cl 2 (g) = +243 kJ/mol.Įxercise 5. Which has the highest lattice energy, Na 3P or Na 2S?Įxercise 4. Order the following ionic compounds from lowest to highest lattice energy. What is the lattice energy for MgF 2?Įxercise 2. Consider the following Born-Haber cycle for MgF 2. Worksheet: Ionic Compounds, Born-Haber Cycle, and Lattice EnergyĮxercise 1. A more extensive list can be found in other tables or in the Handbook of Physics and Chemistry. In the case of NaCl and MgCl 2, the MgCl 2 has the larger lattice energy because the magnesium cation is smaller, and the charge is a +2 rather than a +1 for the sodium ion.īelow is a table with the lattice energies of some ionic compounds. This is because the charges are the same, but the potassium ion is larger than the sodium ion. For example, the lattice energy of NaCl is larger than the lattice energy of KCl. Lattice energies are large when ions are closer together, the distance between the ions is small and when the charges are larger. Coulomb’s law is equal to a constant, k, multiplied by the product of the ion charges, z 1 and z 22, between the ions. Recall, lattice energy is positive meaning it is endothermic. The stronger the bond, the higher the lattice energy. Lattice energy, E lattice is dependent on the strength of the bond between the cation and anion in an ionic bond. The lattice energy is always positive, because it takes energy to separate the ions from the solid. The equation for the lattice energy is the reverse of the equation in Step 5 in the figure below, for the formation of the solid from its ions which releases 787 kJ/mol of energy.Ī Born-Haber cycle allows the calculation of the lattice energy for a solid ionic compound. The process absorbs energy, and is highly endothermic. The NaF distance in NaF, which has the same structure as KF, is 231 pm. The lattice energy of KF is 794 kJ/mol, and the interionic distance is 269 pm. Lattice energy, E lattice is the energy required to separate one mole of a solid ionic compound into its gaseous ions. kJ/mol Ionization energy for K 419 kJ/mol Electron affinity of Cl 349 kJ/mol Bond energy of Cl2 239 kJ/mol Energy of sublimation for K 90. Finish four of the Showdowns and you go to the GRID World Series. Eventually, the discipline culminates in a Showdown, a 2v2 race between your team and the leading team. Some require completing different objectives to unlock subsequent events instead of finishing first. Six disciplines are offered with 104 events in total but you no longer have to finish on top in each event or complete each discipline. You’ve probably looked back on the Career Mode of Grid: Autosport with some trepidation but the new GRID will be changing things up quite a bit. You have touring cars like the Audi RS 3 LMS, prototypes like the McLaren M8D, the good ol’ Chevrolet Camaro GTR.R and even some fictional stock cars like the Dumont Type 37, Jupiter Eagleray Mk5 and Jupiter San Marino Oval. We expect that number to grow when the actual game is released but the sheer range of cars is impressive. Thus far, based on screenshots, videos and impressions, GRID is confirmed to have 69 cars overall. Eurogamer did note that the number of routes is around 82 with a good amount of repetition but courses will be mixed up with different weather conditions like dry and rainy or different times of day. This makes for a total of 92 routes and some of the locations range from Havana and Shanghai to San Francisco. In terms of tracks, GRID will sport 12 overall with eight circuits in four cities. Of course, if the new GRID is anything like the older games, expect there to be a limit to how often Flashback can be used at higher difficulties. This feature allows players to rewind back several seconds and possibly take a turn differently or avoid a crash. It wouldn’t be a Grid game without Flashback. The overall idea, as per game director Christopher Smith, is to bring it back “where it should’ve been in the two sequels” with a focus on racing and motor sport. However, since the 2019 sequel acts as a reboot (despite being the fourth Grid game), it’s simply called GRID. Overtime, it’s taken on its own moniker with Grid 2 and Grid Autosport. Originally, the series started out as Race Driver: Grid, which itself was a new title in the TOCA series (namely TOCA Race Driver). Let’s take a look at the 15 things you should know about GRID before buying. It’s a return to the original game in more ways than one and looks to cater to all kinds of racing fans. Codemasters’ GRID is out on October 11 th for Xbox One, PS4 and PC and will even be releasing for Google Stadia. This usually won’t matter, but you should choose it if your spells are constantly ending before you’ve finished using them. Some spells may even be worse with longer durations, such as Banishment, which benefits from lasting its entire duration. Most combat encounters only last a handful of rounds, so extending a spell’s duration from one to two minutes is a negligible-to-irrelevant buff. The majority of spells have durations that are long enough to get the job done. In my opinion, this is the least useful Metamagic choice. “When you cast a spell that has a duration of 1 minute or longer, you can spend 1 sorcery point to double its duration, to a maximum duration of 24 hours.” Weigh the options and see if you want to have Distant Spell just in case. However, picking Distant Spell means you’re not picking another Metamagic option. Theater of the mind will usually allow you to be in the ballpark for your spell ranges. This may be more useful if you play with actual battle maps. Otiluke’s Freezing Sphere, for example, would have a range of 600 feet. High-level spells get a lot of literal mileage out of this Metamagic because they tend to have much higher casting ranges than low-level spells. This Metamagic may also be useful if you’re in a setting like Eberron that involves airships. However, you might surprise a foe when you cast Counterspell from up to 120 feet away. So if you’re in darkness or close quarters often, Distant Spell will not be useful. If your character is in darkness, they won’t be able to cast spells very far (even with darkvision). It is interesting to extend a touch-range spell to 30 feet since spellcasters often need to stay out of close-quarters combat situations. But many spells of higher level have longer ranges to warrant the high-level spell slots they require, so Distant Spell could make certain spells resemble similar spells of higher levels. If the area isn’t large, the range might not matter. Most encounters I’ve experienced do not take place over large areas, especially in dungeons. I have mixed feelings about Distant Spell. When you cast a spell that has a range of touch, you can spend 1 sorcery point to make the range of the spell 30 feet.” “When you cast a spell that has a range of 5 feet or greater, you can spend 1 sorcery point to double the range of the spell. Your allies will be completely safe from the effect if you use Careful Spell while enemies become incapacitated. Hypnotic Pattern is an excellent spell for using Careful Spell. Blast spells like Fireball will still harm your allies, but if you’re casting a spell that does nothing when a target succeeds on their saving throw, your allies will be completely spared from the spell. If you’re going to use many blasts or AOE spells, your allies will appreciate it if you have this Metamagic. A chosen creature automatically succeeds on its saving throw against the spell.” To do so, you spend 1 sorcery point and choose a number of those creatures up to your Charisma modifier (minimum of one creature). “When you cast a spell that forces other creatures to make a saving throw, you can protect some of those creatures from the spell’s full force. I’ve invented several new Metamagics that I’ll describe later in the article. I’ll run through each Metamagic option in the PHB by providing descriptions of how they transform your spells, followed by choosing and utilizing them. Customized bonus Metamagics make excellent boons to reward Sorcerers. Additionally, I’ve created/compiled a list of homebrew Metamagic options for consideration in your game. This article will help a Sorcerer understand how each Metamagic can optimally enhance their spells. Metamagic is a thematic, useful class feature for Sorcerers, but using Metamagic efficiently can be daunting for players. Sorcerer Metamagic featured art is “Shadow Magic” by 000fesbra000, CC Attribution-Noncommercial-No Derivative Works 3.0 Licenseĭisclaimer: This post contains affiliate links that add gold to our adventuring equipment, at no extra cost to you. The ashes remain suspended in the glass after it is cooled, polished and finished. To create our glass artwork with ashes, we select pieces of clear and transparent glass, scattering the cremation ashes through the glass work which is then melted, encapsulating the ashes forever. Our glass ashes artworks are designed to be durable and will last a lifetime or more with the right care. Unlike resin, glass will not discolour or fade over time or in the sun. For the best experience possible, please call ahead to schedule demos. Resin is unsuitable for memorial artwork as it is a plastic that will degrade over time, allowing the ashes to escape. Glass Cremation Design, Human Ash Keepsake, Glass Ashes Urn, Custom Cremation Art, Loss of Loved One, Pet Memorial Gift, Fill at Home, DIY. This is a superior choice to resin memorial artwork, as it is long-lasting and will not break down over time. The memorial glass is not made from ashes, but rather the ashes are contained within the glass. We have a wide selection of memorials and keepsakes including urns, pet cremation jewelry, keepsakes and memorials. The ashes are then scattered through glass before it is fired in the kilns. Shop Pet Ashes Glass Art for low prices on pet memorials and keepsakes. We select the glass based on the chosen colours and then hand cut the glass and melt it down within kilns to create the sculpture. Each piece of memorial glass is handmade in our workshop by expert glass craftspeople. We offer a wide range of designs, including large-scale wall art and small keepsake pebbles. Cat Angel Garden Art, Cat Pet Memorial (3.6k) 26.00. We can create memorial art glass from the cremation ashes of pets or people. Solid Glass Sea Turtle on a Sea Foam Wave Glass Art, Memorial, Ashes, Celebration Art, Turtle, Ocean, Scuba, Hawaii, Free Shipping (527) Sale Price 184.00 184.00 230.00 Original Price 230.00. Our designs are carefully executed, one-at-a-time, by hand. A piece of memorial glass art is a sculpture or keepsake object made from glass that contains the ashes of a loved one. Glass By Helen creates crematory glass art as an enduring remembrance of your cherished pets. Specifically, she added, an American grit and Swedish style of defense, the implementation of which took some time, but ultimately, was “fairly easy. They picked a coach from another country, and of course I should bring something from that country.” I really want to embrace the words, the body language, and so on. “It took me a while to understand how to reach people. “Football is about communication,” she said. She discussed both the education she’s received about Brazilian culture and how it shapes their distinct style of play, and adjustments she’s guided the team to make that were shaped by her own experience. We deserve to be here just as much as they do.”īrazil start their campaign against Panama on Monday and, before a room buzzing with media from both countries eager to pick her brains, head coach Pia Sundhage reflected on her last four years managing the team. “Playing against Japan, Spain, and Colombia has given us lots of time to analyze and understand,” he said. Preparing for Brazil by playing against other higher-ranked teams was a major part of that. With great partying comes great responsibility, and finding harmony between the two has been one of the main objectives for head coach Nacho Quintana. Asked how the team felt going up against Marta, Quintero pushed back, reminding everyone that “we’re not playing against Marta. Nerves are inevitable, but against a higher ranked Brazilian side, she said: “We’re gonna fight to the very end”. The overarching theme for Panama is balance as they head into their first World Cup match against Brazil.Īldrith Quintero said that Panama is synonymous with happiness, and ever since they punched their ticket to the tournament, they’ve applied a healthy dose of fun and celebration to everything they’ve done - going out to karaoke and making sure they have a good time and enjoy the moment. "We know that once you're on the pitch it's the emotion that takes over so we have to start from doing simple things." "It's gong to be a difficult match against a team that is hard to play," said Bertolini. "Our movement keeps growing (but) it's a very young movement, it's still fragile."Īrgentina may have never won a match at the Women's World Cup but they claimed third-place finishes at the 20 Copa America Femenina, and Bertolini said she expects a tough challenge. We have qualified for two World Cups in a row and I think this is extraordinarily important for the growth in Italy," she said through a translator. "This World Cup is important - just as the previous one - because it does continue the growth process. Italy had not qualified for the tournament in two decades when they made the cut in 2019, reaching the quarter finals under coach Melina Bertolini to match their best performance in the tournament from the 1991 inaugural year.Īnother strong showing in New Zealand and Australia would pay long-term dividends back in Italy, Bertolini told reporters in Auckland on Sunday. Italy are hoping to boost the women's game back home during a World Cup campaign that kicks off against Argentina at Eden Park on Monday. "The message for them is that it is something that is extremely positive it's going to give us so much experience." "They all know they're here at the World Cup," Pedros said via an interpreter. Morocco coach Reynald Pedros said his squad - ranked a whopping 70 places below Germany - are looking forward to the challenge. This is a great milestone for us and we hope that our match with Germany tomorrow will pave the way for other matches." "We feel that we have to shoulder a big responsibility to show a good image, and to show the achievements that the Moroccan football team has made in terms of progress by qualifying. "We are honoured to be the first Arab country to take part. "We are not here just to make up the numbers, but to compete," Chebbak said at a press conference on Sunday ahead of their test against second-ranked Germany. Morocco, who will kick off their campaign against Germany, are one of eight sides making their debut in the expanded 32-team women's global showcase, but Chebbak says their aspirations stretch beyond being happy to be here. Ghizlane Chebbak says Morocco are not at the Women's World Cup to make up the numbers and are ready to shoulder the responsibility of being the first Arab country to take part as they prepare to make their debut on Monday. Starting this quest will fail Road to Freedom or Tradecraft if it has not yet been completed. The Railroad main quest ending will be unavailable due to that requiring the Sole Survivor to infiltrate the Institute, though it is still possible to complete Railroad side quests. This results in them being locked out of the Institute and their only choice will be to work with the Minutemen or the Brotherhood of Steel. If one kills Father immediately after meeting him, they need to download the data onto the network scanner in order to leave.That quest can only start after the end of this quest, having left the Institute on good terms, and returned to Elder Maxson. During this quest no progress can be made with Dr.They rejoin the player when they emerge at the CIT ruins. The current companion is unavailable during this quest.I've turned down his offer to join him, and now have no choice but to leave the Institute. I've found Shaun, who is now sixty years old and the Director of the Institute. Use the Network Scanner Holotape - If enlisted the Railroad to help build the signal interceptor, or if declined to join InstituteĮxit the Institute - If declined to join the Institute I've accepted his invitation to join the Institute, and need to introduce myself to the department heads. I've found my son, who is now sixty years old and the leader of the Institute. I need to find my son, and then find a way out.ĭone talking to Shaun, trigger Father's entrance It is possible to speak to Father again and change one's mind only if combat has not been detected and if one has not yet exited the Institute. ruins, completing Institutionalized, and will never be able to return to the Institute. Regardless of whether combat was initiated, or whether one leaves peacefully, on entering the relay room the player character will be automatically teleported to the C.I.T. The door to the relay room is locked unless the network scanner holotape was previously used (in any Institute terminal) if necessary, complete the network scan now to open the relay room door. If some form of agreement has been reached with Father before initiating combat, synths and Institute personnel will also enter through the now-unlocked doors to attack the player character. The number of spawned synths increases as time passes. If combat is detected in the Institute a number of synths will spawn along the exit route to the relay room. Alternatively, one can refuse to work with the Institute, in which case Father will tell the player to leave, or attack Father, to end the quest on hostile terms and be banished from the Institute. If one decided to enlist the help of the Railroad in building the signal interceptor, then it is necessary to complete the network scan before this quest is resolved. After speaking to these individuals, the quest is resolved and the following quest, Synth Retention, is started automatically. Speak to Clayton Holdren, Allie Filmore, Justin Ayo, and Madison Li, the latter of which installs a relay into the player's Pip-Boy, allowing fast travel to and from the Institute upon completion of this quest. If they disagree to join, the doors remain locked and it is not possible to proceed beyond Father's quarters. After speaking with him and agreeing to join the Institute (alternatively stalling by telling him they want to think about it), the player is free to explore the facility. He will then initiate a conversation with the Sole Survivor which reveals that he is the real Shaun and the director of the Institute, as well as several other details regarding the Sole Survivor's situation and the details surrounding his initial kidnapping by the Institute. When discovered to be a 10-year-old synthetic Shaun, a man named Father enters the room and shuts him down with a code phrase. If using the relay room to depart (rather than using the Pip-Boy directly to fast travel) then the network scan must be carried out, or the doors to the relay room will not open.Īfter following the voice through the empty Institute corridors and up another elevator, the Sole Survivor eventually enters a room to find a scared and confused child. It is possible to acquire the required data using the holotape provided for Inside Job or Outside the Wire at this time, as the console is right at the entry/exit point of the Institute. When the elevator opens, the door to the relay room locks closed, and the quest begins. The voice invites the player to enter an elevator. After successfully teleporting into the Institute, the Sole Survivor will be greeted by a voice coming from hidden speakers. Henceforth, however, Waterhouse's interest centred more and more on gardens and foliage and figures seated on the ground, among plants and flowers". Waterhouse relied on flights of steps to drive a number of his more ambitious compositions in the 1880s, most notably St Eulalia 1885 (London, Tate Britain, Millbank), Mariamne, 1887 (New York, Forbes Magazine Collection) and A flower market, old Rome (Private collection). Diogenes, 18th Century Italian School Large 18th century Italian school portrait of the Greek philosopher Diogenes, oil on canvas. Moreover, the spatial arrangements, a sunken ledge below street-level beside a flight of steps, as well as the curiosity of the young women, who lean forward to catch a glimpse of the cranky old man, serve to underline his gloomy rejection of the world the better to serve some immediate practical good. The Greek philosopher Diogenes (404-323 BC) is seated in his abode, the earthenware tub, in the Metroon. "The treatment of marble in Diogenes, and the faithful reconstruction of the Doric temple architecture in the background (Diogenes' tub was according to tradition borrowed from the Temple of the Mother of the Gods), even the peculiarly Japanese-looking sun-shades, as well as numerous details of costume, were all executed with great care. Diogenes by Jean-Léon Gérôme depicts the Greek Philosopher Diogenes (404 323 BC) seated in the shelter he used during the night. According to Angus Trumble, this painting closes the stage in his career when "the meticulous archaeological techniques of Lawrence Alma-Tadema" influenced the artist. 120P i.e.In Waterhouse's painting, Diogenes, the ancient ascetic philosopher who lived in a tub and carried a lantern, looking for an honest man, provides a striking contrast to the attractive young women and their perfectly blooming flowers. Diogenes was a controversial figure with a reputation for sleeping and eating wherever he chose in a highly non-traditional fashion. Portrait Of Diogenes stock photos are available in a variety of sizes and formats to fit your needs. Having abandoned his search for an honest. Diogenes by John William Waterhouse depicts Diogenes the Cynic (412 323 BC), who was a Greek philosopher. Browse Getty Images premium collection of high-quality, authentic Portrait Of Diogenes stock photos, royalty-free images, and pictures. A large painting by Van Mol in Orlans (fig. The Diogenes painting, which falls in the middle of this series, depicts the Greek philosopher in his later years. Find more prominent pieces of history painting at best visual art. 80F i.e.: 145 cm x 113 cm x 2 cm / 57" x 44"5 x 0"8 Although this is Van Mols masterpiece it fits into his oeuvre quite comfortably. Diogenes was created in 1860 by Jean-Leon Gerome in Academicism style. Two possible dimensions (to be selected from the drop-down menu): Find more prominent pieces of history painting at best visual art database. Other dimensions possible, please contact us for quotes and deadlines. ‘Diogenes’ was created in 1882 by John William Waterhouse in Romanticism style. The fresco was painted between 15 as a part of Raphael's commission to decorate the rooms now known as the Stanze di Raffaello, in the Apostolic Palace in the Vatican. Very nice achievement that will be perfect to dress your walls. The School of Athens ( Italian: Scuola di Atene) is a fresco by the Italian Renaissance artist Raphael. Diogenes carried the lamp throughout the day, arguing to be looking for a man. This fantastic finely made painting will have the extreme elegance to add an extra touch to your interior decoration by decorating your walls with the elegance of the old. One can see the ceramic jar lodgings together with the lamp on the painting. This work shows an extraordinary pictorial quality and particularly elaborated with exceptional precision. RMKECK3F Diogenes Throwing Away his Bowl on Seeing a Peasant Drink from his Hand, Woodcut Engraving from the Original Painting by Nicolas Poussin, The Masterpieces of French Art by Louis Viardot, Published by Gravure Goupil et Cie, Paris, 1882, Gebbie & Co. The original of this work was made in 1560-1570. This painting represents "The philosopher Diogenes throwing his bowl" painted by Giovanni Paolo Pannini (Italian painter). Superb painting reproduction on canvas with aged and cracked effect, mounted on an aged wooden frame also patinated, as if this painting had been discovered while searching in an old attic, a work of art hidden out of sight and preserved preciously.
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